Preheat the oven to 329°F (165°C) and line an 8 in x 8 in baking pan with parchment paper.
In a heatproof bowl, combine 180 g butter and 320 g chocolate. Place the bowl over a pot of simmering water (ensure the water doesn’t touch the bowl) and stir occasionally until smooth and melted. Remove from heat and let it cool slightly.
In a separate bowl, whisk together 180 g granulated sugar, 80 g brown sugar, and 4 eggs. Whisk for 2–3 minutes until the mixture becomes light, thick, and smooth. This step helps create the signature crinkly top.
In another bowl, sift together 120 g all-purpose flour, 50 g cocoa powder, and 2 g salt.
Add the melted chocolate-butter mixture to the egg-sugar mixture and stir until smooth.
Gradually fold in the flour-cocoa mixture until just combined. Some streaks of flour are fine—do not overmix. Fold in 120 g chocolate chunks until evenly distributed throughout the batter.